Premium
High‐resolution solid‐state 73 Ge NMR spectra of hexacoordinated germanium compounds
Author(s) -
Takeuchi Yoshito,
Nishikawa Miki,
Yamamoto Hiroshi
Publication year - 2004
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.1486
Subject(s) - chemistry , germanium , magic angle spinning , nmr spectra database , solid state nuclear magnetic resonance , spectral line , magic angle , nuclear magnetic resonance spectroscopy , carbon 13 nmr satellite , chemical shift , high resolution , resolution (logic) , solid state , crystallography , fluorine 19 nmr , nuclear magnetic resonance , stereochemistry , silicon , organic chemistry , physics , remote sensing , astronomy , artificial intelligence , computer science , geology
High‐resolution solid‐state magic angle spinning 73 Ge NMR spectra of hexavalent germanium compounds, i.e. diiodogermylene ( 1a ) and bis(1‐pyrrolyl)( meso ‐tetraphenylporphyrinato)germanium ( 3a ), were determined. To the best of our knowledge, this is the first example of high‐resolution solid‐state 73 Ge NMR spectra of hexacoordinated germanium nuclei. The symmetry requirement for observation of high‐resolution solid‐state 73 Ge NMR spectra is discussed. Copyright © 2004 John Wiley & Sons, Ltd.