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13 C NMR studies on trifluoroacetyl derivatives of 2‐acetamido‐2‐deoxyhexoses
Author(s) -
Ranganathan M.,
Balaram P.
Publication year - 1984
Publication title -
organic magnetic resonance
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0030-4921
DOI - 10.1002/mrc.1270221110
Subject(s) - chemical shift , chemistry , mannose , galactose , carbon 13 nmr , medicinal chemistry , stereochemistry , organic chemistry
The effect of trifluoroacetylation on the 13 C chemical shifts of 2‐acetamido‐2‐deoxyhexoses was examined. Studies of the 2‐acetamido derivatives of glucose, galactose and mannose established that no regular trend in the 13 C shifts occurred on trifluoroacetylation. This was in marked contrast to the results obtained for the 1 H chemical shifts.
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