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Glucosidation shifts of allylic and benzylic alcohols in 13 C NMR spectroscopy
Author(s) -
Horibe Isao,
Seo Shujiro,
Yoshimura Yohko,
Tori Kazuo
Publication year - 1984
Publication title -
organic magnetic resonance
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0030-4921
DOI - 10.1002/mrc.1270220706
Subject(s) - allylic rearrangement , chemistry , nuclear magnetic resonance spectroscopy , chemical shift , nmr spectra database , spectroscopy , carbon 13 nmr , two dimensional nuclear magnetic resonance spectroscopy , absolute configuration , organic chemistry , spectral line , stereochemistry , catalysis , physics , quantum mechanics , astronomy
The 13 C FT NMR spectra of β‐ D ‐glucopyranosides (including their tetraacetates) of several secondary allylic and benzylic alcohols were compared with those of methyl β‐ D ‐glucopyranoside and the corresponding parent alcohols. The characeristic glucosidation shifts observed for these alcohols may be applicable to the determination of the absolute configuration of the hydroxy group in these alcohols.