z-logo
Premium
Application of NMR spectroscopy of chiral association complexes. 13 —electron donor–acceptor complexes between racemic carbazolo[3,4‐ c ]carbazoles and an optically active acceptor
Author(s) -
İçli Siddik,
Burgemeister Thomas,
Mannschreck Albrecht,
Zander Maximilian
Publication year - 1982
Publication title -
organic magnetic resonance
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0030-4921
DOI - 10.1002/mrc.1270200306
Subject(s) - diastereomer , chirality (physics) , acceptor , chemistry , spectroscopy , optically active , nuclear magnetic resonance spectroscopy , electron donor , electron acceptor , proton nmr , stereochemistry , derivative (finance) , photochemistry , crystallography , catalysis , organic chemistry , chiral symmetry , physics , condensed matter physics , quantum mechanics , nambu–jona lasinio model , quark , financial economics , economics
Strong electron donor–acceptor (EDA) association between carbazolo[3,4‐ c ]carbazoles and an optically active tetranitrofluorenone derivative was detected by UV–visible spectroscopy and by 1 H NMR shifts. 1 H NMR splittings at low temperatures are due to diastereomeric association complexes and, thus, prove the chirality of carbazolocarbazoles.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here