Deuterium isotope effects on one‐bond carbon, hydrogen coupling constants | Zendy

Everett Jeremy R. | Zendy

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Deuterium isotope effects on one‐bond carbon, hydrogen coupling constants

Author(s) -

Everett Jeremy R.

Publication year - 1982

Publication title -

organic magnetic resonance

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0030-4921

DOI - 10.1002/mrc.1270190313

Subject(s) - deuterium , kinetic isotope effect , isotope , chemistry , hydrogen , deuterium nmr , molecule , coupling constant , carbon fibers , carbon 13 , coupling (piping) , computational chemistry , materials science , atomic physics , nuclear physics , physics , organic chemistry , particle physics , composite number , composite material , metallurgy

Small, negative deuterium isotope effects on 1 J (CH) have been found for a variety of simple organic molecules. These new experimental data support theoretical calculations and suggestions based on previous imprecise experimental measurements. The deuterium isotope effects upon the 13 C chemical shifts were also measured with high precision.

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