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Mercury‐199 NMR chemical shifts in substituted diphenylmercury and phenylmercuric chloride
Author(s) -
Wells Peter R.,
Hawker Darryl W.
Publication year - 1981
Publication title -
organic magnetic resonance
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0030-4921
DOI - 10.1002/mrc.1270170107
Subject(s) - chemical shift , mercury (programming language) , chemistry , chloride , nuclear chemistry , inorganic chemistry , computational chemistry , organic chemistry , computer science , programming language
The influence of substituents on the 199 Hg chemical shifts of some Ar 2 Hg and ArHgCl species in 1:1 CDCl 3 : CH 2 Cl 2 and in CDCl 3 : DMSO solutions is reported. The effects are substantial and are in the direction of electron withdrawal producing increased shielding (i.e. shifts towards higher field).