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Carbon‐13 and aluminium‐27 nuclear spin relaxation in triethylaluminum
Author(s) -
Vestin U.,
Kowalewski J.,
Henriksson U.
Publication year - 1981
Publication title -
organic magnetic resonance
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0030-4921
DOI - 10.1002/mrc.1270160211
Subject(s) - aluminium , nuclear overhauser effect , relaxation (psychology) , toluene , atmospheric temperature range , spin–lattice relaxation , chemistry , nuclear magnetic resonance , carbon fibers , molecule , materials science , analytical chemistry (journal) , physics , organic chemistry , thermodynamics , psychology , social psychology , nuclear quadrupole resonance , composite number , composite material
Carbon‐13 spin–lattice relaxation times and nuclear Overhauser enhancement factors are reported for triethylaluminium in toluene‐ d 8 solution in the temperature interval 208–318 K. Aluminium‐27 linewidths are reported for the same solution in the temperature range 212–334 K. The effective correlation times at different positions in the molecule are determined and used for qualitative discussion of internal motions.