The configuration and conformation of the tricyclo[4.4.1.1 2,5 ]dodecan‐11‐ols determined by  1 H NMR spectroscopy using the shift reagent Eu(fod) 3 | Zendy

Mason Timothy J. | Zendy

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The configuration and conformation of the tricyclo[4.4.1.1 2,5 ]dodecan‐11‐ols determined by 1 H NMR spectroscopy using the shift reagent Eu(fod) 3

Author(s) -

Mason Timothy J.

Publication year - 1981

Publication title -

organic magnetic resonance

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0030-4921

DOI - 10.1002/mrc.1270150324

Subject(s) - cyclopentadiene , tropone , reagent , cycloaddition , chemistry , proton , nuclear magnetic resonance spectroscopy , spectroscopy , proton nmr , spectral line , crystallography , nmr spectra database , stereochemistry , catalysis , organic chemistry , physics , quantum mechanics , astronomy

The isomeric tricyclo[4.4.1.1 2,5 ]dodecan‐11‐ols have been synthesized from the (6+4) cycloaddition product of tropone with cyclopentadiene. The configuration and conformation of each isomer was determined from the proton shift gradients induced in the olefinic proton signals in the 1 H NMR spectra of intermediate compounds by Eu(fod) 3 .

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