The conformational dependence of vicinal  13 C 13 C spin–spin coupling constants in alicyclic compounds | Zendy

Berger Stefan | Zendy

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The conformational dependence of vicinal 13 C 13 C spin–spin coupling constants in alicyclic compounds

Author(s) -

Berger Stefan

Publication year - 1980

Publication title -

organic magnetic resonance

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0030-4921

DOI - 10.1002/mrc.1270140116

Subject(s) - vicinal , dihedral angle , alicyclic compound , coupling constant , chemistry , spin (aerodynamics) , crystallography , atom (system on chip) , carbon atom , computational chemistry , ring (chemistry) , molecule , physics , organic chemistry , thermodynamics , hydrogen bond , particle physics , computer science , embedded system

A series of alicyclic compounds with dihedral angles of 0°, 60°, 90°, 120° and 180° between a 13 C‐labelled carbon atom and a carbon atom separated by three bonds from the label has been synthesized. The vicinal 13 C 13 C spin coupling constants were measured, and from the results a Karplus‐type relationship between 13 C 13 C spin coupling and dihedral angle is proposed.

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