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Substituent effects on 13 C NMR chemical shifts in the saturated framework of primary aliphatic derivatives
Author(s) -
Ejchart Andrzej
Publication year - 1980
Publication title -
organic magnetic resonance
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0030-4921
DOI - 10.1002/mrc.1270130515
Subject(s) - chemical shift , substituent , primary (astronomy) , chemistry , computational chemistry , carbon 13 nmr , organic chemistry , physics , astronomy
A general equation describing the effect of substituents on α‐carbons in a saturated framework was developed from 13 C chemical shifts obtained under uniform conditions for selected aliphatic compounds. Experimental correlations for β‐ and γ‐carbons and a discussion of the results are presented.
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