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195 Pt NMR studies on monomer and dimer complexes. Observation of PtPt coupling constants
Author(s) -
Soulié J.,
Lallemand J. Y.,
Rao R. C.
Publication year - 1979
Publication title -
organic magnetic resonance
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0030-4921
DOI - 10.1002/mrc.1270120205
Subject(s) - platinum , dimer , monomer , chemistry , coupling constant , crystallography , polymer , physics , organic chemistry , catalysis , particle physics
Abstract Various platinum complexes have been studied by 195 Pt FT NMR. Long range J ( 31 P 195 Pt) and J ( 195 Pt 195 Pt) are observed in dinuclear complexes. The value of 1 J ( 31 P 195 Pt) in monomeric and dimeric complexes is shown to depend mainly upon the Pt—P bond length.