Premium
Time‐dependence of the polarized intensity ratio in CIDNP investigations
Author(s) -
Kende Imre
Publication year - 1978
Publication title -
organic magnetic resonance
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0030-4921
DOI - 10.1002/mrc.1270110202
Subject(s) - cidnp , kinetic energy , intensity (physics) , kinetics , product (mathematics) , basis (linear algebra) , polarization (electrochemistry) , materials science , analytical chemistry (journal) , chemistry , physics , optics , chromatography , mathematics , classical mechanics , geometry
The time‐dependence of the polarized intensity ratio within a product molecule has been studied by a kinetic method. The kinetic analysis of polarized product formation shows that considerable changes in CIDNP ratios occur during the reaction but characteristic curves can be obtained under different experimental conditions. A method is proposed to evaluate the relative enhancement coefficients on the basis of these characteristic curves, and to obtain information on the kinetics of the reaction.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom