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A Karplus‐type relationship for the vicinal coupling 3 J (CCCP) in phosphonates
Author(s) -
Thiem Joachim,
Meyer Bernd
Publication year - 1978
Publication title -
organic magnetic resonance
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0030-4921
DOI - 10.1002/mrc.1270110115
Subject(s) - vicinal , phosphonate , coupling constant , type (biology) , derivative (finance) , coupling (piping) , chemistry , function (biology) , computational chemistry , stereochemistry , crystallography , physics , quantum mechanics , materials science , organic chemistry , ecology , evolutionary biology , financial economics , metallurgy , economics , biology
The complete assignment of the 13 C NMR spectrum of a conformationally rigid camphane phosphonate derivative leads to a Karplus‐type function for the vicinal 3 J (CCCP) coupling constants in phosphonates. The general applicability of this relationship is demonstrated.