13 C NMR: Stereochemical dependence of the one‐bond coupling constant  1  J   13 CH in α‐halogenoketones | Zendy

Cantacuzene J. | Zendy; Jantzen R. | Zendy; Tordeux M. | Zendy; Chachaty C. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

13 C NMR: Stereochemical dependence of the one‐bond coupling constant 1 J 13 CH in α‐halogenoketones

Author(s) -

Cantacuzene J.,

Jantzen R.,

Tordeux M.,

Chachaty C.

Publication year - 1975

Publication title -

organic magnetic resonance

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0030-4921

DOI - 10.1002/mrc.1270070811

Subject(s) - coupling constant , chemistry , carbon 13 , equilibrium constant , coupling (piping) , constant (computer programming) , j coupling , crystallography , stereochemistry , computational chemistry , nuclear magnetic resonance spectroscopy , physics , nuclear physics , materials science , quantum mechanics , computer science , programming language , metallurgy

The one‐bond coupling constant 1 J 13 CH for the halogenated carbon in α‐halogenocyclohexanones is more important when the CH bond is in the equatorial then in the axial position. When a conformational equilibrium is present, the resulting coupling is a linear function of the equilibrium constant.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research