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An example of hydrate‐keto equilibrium
Author(s) -
Dhingra M. M.,
Tatta K. R.
Publication year - 1975
Publication title -
organic magnetic resonance
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0030-4921
DOI - 10.1002/mrc.1270070413
Subject(s) - hydrate , acetone , chemistry , ether , clathrate hydrate , resonance (particle physics) , thermodynamics , organic chemistry , physics , particle physics
The hydrate of 1,1,1,5,5,5‐hexafluoro‐2‐hydroxy‐2‐methylpentan‐4‐one has been shown to exist in a hydrate‐keto equilibrium in acetone and ether solutions using 1 H and 19 F magnetic resonance. The equilibrium percentages of the keto and hydrate forms as determined from 19 F resonance are 30 and 70, respectively.