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Molecular motions in alicyclic compounds
Author(s) -
Levy G. C.,
Komoroski R. A.,
Echols R. E.
Publication year - 1975
Publication title -
organic magnetic resonance
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0030-4921
DOI - 10.1002/mrc.1270070406
Subject(s) - alicyclic compound , anisotropy , ring size , rotation (mathematics) , ring (chemistry) , relaxation (psychology) , chemistry , chemical physics , materials science , computational chemistry , nuclear magnetic resonance , organic chemistry , crystallography , physics , mathematics , geometry , optics , social psychology , psychology
Carbon‐13 spin‐lattice relaxation times and chemical shifts are reported for a number of cyclic alcohols and the corresponding methyl ethers. The overall rotation of the alcohols was found to be considerably more anisotropic than that of the methyl ethers. Anisotropic motion becomes less pronounced in both series as ring size increases.