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Intrinsic carbon‐13 NMR solvent shifts in hydrocarbons. Relevance of long range substituent parameters
Author(s) -
Wilson A. R. N.,
van de Ven L. J. M.,
de Haan J. W.
Publication year - 1974
Publication title -
organic magnetic resonance
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0030-4921
DOI - 10.1002/mrc.1270061111
Subject(s) - substituent , chemical shift , solvent , chemistry , solvent effects , carbon fibers , carbon 13 nmr , alkane , computational chemistry , organic chemistry , hydrocarbon , materials science , composite number , composite material
Carbon‐13 NMR chemical shifts have been measured in a number of binary mixtures of normal alkanes. Intrinsic solvent shifts are deduced from the shifts and the relevance of some small substituent effects in alkanes is discussed. A comparison is made between solvent effects and thermally induced chemical shift differences in alkanes.