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Evidence from fluorine and proton NMR spectra for restricted rotation about the PO bond in some steroidal phosphorofluoridates
Author(s) -
Cooper G. H.,
Chittenden Rosemary A.
Publication year - 1974
Publication title -
organic magnetic resonance
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0030-4921
DOI - 10.1002/mrc.1270061015
Subject(s) - rotation (mathematics) , spectral line , proton , chemistry , nmr spectra database , crystallography , fluorine , fluorine 19 nmr , salient , carbon 13 nmr satellite , carbon 13 nmr , proton nmr , nuclear magnetic resonance , nuclear magnetic resonance spectroscopy , stereochemistry , physics , organic chemistry , mathematics , geometry , nuclear physics , quantum mechanics , computer science , artificial intelligence
The salient features of the 19 F and 1 H NMR spectra of seven steroidal phosphorofluoridates are presented and evidence for restricted rotation, obtained from high temperature studies and deuteration experiments, is discussed.