CIDNP effects in various magnetic fields during the reaction of substituted benzyl chlorides with  n ‐butyllithium | Zendy

Sagdeev R. Z. | Zendy; Molin Yu. N. | Zendy; Salikhov K. M. | Zendy; Leshina T. V. | Zendy; Kamha M. A. | Zendy; Shein S. M. | Zendy

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CIDNP effects in various magnetic fields during the reaction of substituted benzyl chlorides with n ‐butyllithium

Author(s) -

Sagdeev R. Z.,

Molin Yu. N.,

Salikhov K. M.,

Leshina T. V.,

Kamha M. A.,

Shein S. M.

Publication year - 1973

Publication title -

organic magnetic resonance

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0030-4921

DOI - 10.1002/mrc.1270051211

Subject(s) - cidnp , butyllithium , chemistry , hexane , photochemistry , physics , medicinal chemistry , organic chemistry , polarization (electrochemistry)

We detected and studied CIDNP effects in the reaction of substituted benzyl chlorides with n ‐butyllithium in hexane (Scheme 1) in various magnetic fields (from 0·5 Oe to about 25,000 Oe). The polarisation of 19 F nuclei in the reaction of p ‐F‐benzyl chloride in strong fields has been observed by Rakshys. 1 We succeeded, however, in finding the CIDNP effects for both 19 F and 1 H in all the reactions investigated. The CIDNP effects observed offer a number of remarkable features; therefore, a detailed analysis of these effects can be useful for a better understanding of the nature of CIDNP.

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