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Kinetics of chemical polarisation of 31 P nuclei in the reactions of phosphites
Author(s) -
Pobedimsky D. G.,
Kirpichnikov P. A.,
Samitov Yu. Yu.,
Goldfarb E. I.
Publication year - 1973
Publication title -
organic magnetic resonance
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0030-4921
DOI - 10.1002/mrc.1270051012
Subject(s) - chemistry , peroxide , chemical reaction , chemical kinetics , kinetics , interpretation (philosophy) , radiochemistry , physics , organic chemistry , quantum mechanics , computer science , programming language
Chemical polarisation of 31 P nuclei was discovered and quantitatively measured in the peroxide‐phosphite system. The qualitative interpretation of the net polarisation of 31 P nuclei and of its sign in the products of the radical reactions in the presence of phosphites is given within the frame of the radical pair model.