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Chemical polarisation of electrons in redox reactions
Author(s) -
Shuvalov V. F.,
Stunzhas P. A.,
Moravskii A. P.
Publication year - 1973
Publication title -
organic magnetic resonance
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0030-4921
DOI - 10.1002/mrc.1270050709
Subject(s) - isobutyric acid , redox , chemistry , recombination , electron , photochemistry , radical , inorganic chemistry , physics , organic chemistry , biochemistry , quantum mechanics , gene
In the system Ti(III)H 2 O 2 RH (RH is isobutyric acid or isopropanol) the concentration and polarisation of the β‐radical decreases during the reaction, while the polarisation of the α‐radical increases with the decrease of the α‐radical concentration. The second fact is not in accordance with Adrian's model of inducing the polarisation in redox systems during the radical recombination process.