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13 C CIDNP effects in the decomposition products of acetylbenzoyl peroxide
Author(s) -
Kessenikh A. V.,
Petrovskii P. V.,
Rykov S. V.
Publication year - 1973
Publication title -
organic magnetic resonance
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0030-4921
DOI - 10.1002/mrc.1270050507
Subject(s) - cidnp , cyclohexanone , decomposition , chemistry , peroxide , benzoyl peroxide , photochemistry , solvent , chemical decomposition , radical , organic chemistry , catalysis , polymer , polymerization
13 C CIDNP effects in the decomposition of acetylbenzoyl peroxide in cyclohexanone are described. A comparison between our data, and those on the 1 H CIDNP effects and the 13 C CIDNP observed in the decomposition of ABP in C 2 Cl 4 1 leads to definite conclusions on the signs of the HFI constants of the benzoyl radical and to an identification of the separate products of the radical‐induced reactions with the solvent.