Novel NMR aspects of tertiary phosphine complexes of Ru(II) etioporphyrin I | Zendy

Licoccia Silvia | Zendy; Paci Maurizio | Zendy; Paolesse Roberto | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Novel NMR aspects of tertiary phosphine complexes of Ru(II) etioporphyrin I

Author(s) -

Licoccia Silvia,

Paci Maurizio,

Paolesse Roberto

Publication year - 1995

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.1260331203

Subject(s) - chemistry , phosphine , steric effects , multiplicity (mathematics) , proton nmr , ruthenium , stereochemistry , nmr spectra database , nuclear magnetic resonance spectroscopy , two dimensional nuclear magnetic resonance spectroscopy , spectral line , organic chemistry , catalysis , physics , mathematics , astronomy , mathematical analysis

The synthesis and characterization of hexacoordinated ruthenium complexes of etioporphyrin I (EP) of general formula [(EP)RuL 2 ] (L = teriary phosphine) and of the pentacoordinated complex [(EP)Ru(PPh 3 )] are reported. The multiplicity observed in the 1 H NMR spectra of complexes is discussed on the basis of the steric interactions between the axial ligands and the macrocycle.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research