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Solid‐state 13 C NMR spectroscopy. 2 ‐titanium tetrachloride‐ketone complexes. Structure and mechanism of isomerization
Author(s) -
Maier Günther,
Kalinowski HansOtto,
Weber Claudia,
Henrich Markus
Publication year - 1995
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.1260330412
Subject(s) - chemistry , titanium tetrachloride , isomerization , tetrachloride , ketone , nuclear magnetic resonance spectroscopy , titanium , proton nmr , spectroscopy , photochemistry , nmr spectra database , spectral line , organic chemistry , catalysis , physics , quantum mechanics , astronomy , tin
The solid‐state 13 C NMR spectra of a series of titanium tetrachloride‐ketone and titanium tetrachloride‐ester complexes are presented. The kind of complexation is discussed. The activation energy and the mechanism (planar inversion) for the syn‐anti isomerization at the oxygen atom was evaluated.