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Pulsed field gradient one‐dimensional NMR selective ROE and TOCSY experiments
Author(s) -
Dalvit Claudio,
Bovermann Günter
Publication year - 1995
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.1260330214
Subject(s) - chemistry , pulsed field gradient , pulse sequence , field (mathematics) , analytical chemistry (journal) , nuclear magnetic resonance spectroscopy , molecule , nuclear magnetic resonance , stereochemistry , chromatography , physics , organic chemistry , mathematics , pure mathematics
A pulsed field gradient one‐dimensional NMR selective ROE (rotating frame NOE) experiment was designed and successfully tested. The resulting spectra are of high quality and devoid of artefacts. Hence reliable quantification of very weak ROEs necessary for the three‐dimensional structure determination of a molecule is now possible. A similar experiment was designed for the selective 1D TOCSY pulse sequence.