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Application of 19 F NMR spectroscopy to the study of equilibrium dynamics of uranyl(2+)‐fluoride complexes
Author(s) -
Szabó ZoltáN,
Glaser Julius
Publication year - 1995
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.1260330106
Subject(s) - chemistry , uranyl , fluoride , aqueous solution , nuclear magnetic resonance spectroscopy , relaxation (psychology) , magnetization transfer , spectroscopy , fluorine 19 nmr , magnetization , equilibrium constant , inorganic chemistry , analytical chemistry (journal) , computational chemistry , ion , organic chemistry , medicine , social psychology , psychology , physics , quantum mechanics , magnetic field , magnetic resonance imaging , radiology
One‐ and two‐dimensional magnetization‐transfer 19 F NMR methods were applied in a quantitative study of the fluoride exchange for uranyl(2+)‐fluoride complexes in aqueous solution. The applicability of these techniques and the classical lineshape analysis is discussed, and the quality of the results (rate constants and relaxation rates) obtained by the three methods is compared.