Detailed characterization by, two‐dimensional NMR of two unusual bicyclo [2.2.2]octenedione derivatives produced by the reaction of perezone with thiourea | Zendy

Reynolds William F. | Zendy; Yu Margaret | Zendy; Ortiz Benjamin | Zendy; Rodriguez Angel | Zendy; Yuste Francisco | Zendy; Walls Fernando | Zendy; Enriquez Raul G. | Zendy; Gnecco Dino | Zendy

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Detailed characterization by, two‐dimensional NMR of two unusual bicyclo [2.2.2]octenedione derivatives produced by the reaction of perezone with thiourea

Author(s) -

Reynolds William F.,

Yu Margaret,

Ortiz Benjamin,

Rodriguez Angel,

Yuste Francisco,

Walls Fernando,

Enriquez Raul G.,

Gnecco Dino

Publication year - 1995

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.1260330103

Subject(s) - chemistry , thiourea , dept , bicyclic molecule , two dimensional nuclear magnetic resonance spectroscopy , carbon 13 nmr , stereochemistry , proton nmr , organic chemistry

A combination of NMR experiments, including 13 C and 15 N DEPT, COSY, NOESY, HMQC and HMBC experiments, was used to assign the structures and stereochemistries of two isomeric bicyclo[2.2.2]octenedione derivatives produced by the reaction of perezone with thiourea, followed by treatment with silica gel. A possible mechanism of the reaction is suggested.

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