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Complete 1 H and 13 C NMR spectral assignment of pentacyclo [6.4.0.0 2,6 .0 5,9 .0 4,12 ]dodecane derivatives and structure elucidation of pentacyclo [6.4.0.0 2,6 .0 3,11 .0 5,9 ]dodecane
Author(s) -
Martins F. J. C.,
Coetzee G. H.,
Fourie L.,
Venter H. J.,
Viljoen A. M.,
Wessels P. L.
Publication year - 1993
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.1260310611
Subject(s) - chemistry , dodecane , nuclear magnetic resonance spectroscopy , nmr spectra database , hydrocarbon , stereochemistry , crystallography , spectral line , nuclear chemistry , organic chemistry , physics , astronomy
Treatment of pentacyclo[6.4.0.0 2,6 .0 5,9 .0 4,12 ]dodecane‐2‐ol with concentrated sulphuric acid produced the rearranged hydrocarbon pentacyclo[6.4.0.0 2,6 .0 3,11 .0 5,9 ]dodecane as the main product. High‐field 1 H and 13 C NMR techniques were used in the structure elucidation and assignment of the different NMR resonances of these two and related compounds.