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Improved strategy for sequence‐specific 13 C NMR assignments in [d(CGTACGTACG)] 2
Author(s) -
Wang Ke Yu,
Heffron Gregory J.,
Bishop Karl D.,
Levy George C.,
Garbesi Anna M.,
Tondelli Luisa,
Medley James H.,
Borer Philip N.
Publication year - 1992
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.1260300504
Subject(s) - heteronuclear molecule , chemistry , coherence (philosophical gambling strategy) , sequence (biology) , pulse sequence , nuclear magnetic resonance spectroscopy , heteronuclear single quantum coherence spectroscopy , analytical chemistry (journal) , nuclear magnetic resonance , stereochemistry , organic chemistry , quantum mechanics , physics , biochemistry
13 C resonances of [d(CGTACGTACG)] 2 were assigned by heteronuclear multiple quantum coherence and longrange heteronuclear multiple coherence. The maximum likelihood method was used for the sugar regions of the HMQC spectrum, which made it possible to assign unambiguously all the C‐2′ carbons and some of the C‐5′ carbons.