13 C and  195 Pt NMR of  para ‐substituted  N , N ‐dialkyl‐ N ′‐benzoylthioureas and their  cis ‐[ML 2 ] complexes, M = Pd(II) and Pt(II) | Zendy

Koch Klaus R. | Zendy; Matoetoe Mangaka C. | Zendy

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13 C and 195 Pt NMR of para ‐substituted N , N ‐dialkyl‐ N ′‐benzoylthioureas and their cis ‐[ML 2 ] complexes, M = Pd(II) and Pt(II)

Author(s) -

Koch Klaus R.,

Matoetoe Mangaka C.

Publication year - 1991

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.1260291114

Subject(s) - chemistry , carbon 13 nmr , thio , ion , carbon atom , medicinal chemistry , urea , atom (system on chip) , crystallography , stereochemistry , organic chemistry , alkyl , computer science , embedded system

A series of neutral cis ‐[ML 2 ] complexes, where M = Pd(II) and Pt(II) and L = para ‐substituted N , N ‐dialkyl‐ N ′‐benzoyl‐thio‐urea anion, were examined by means of 13 C and 195 Pt NMR. Unambiguous assignment of the thiocarbonyl carbon atom in these complexes was achieved with 13 C isotopic enrichment and the resolved n J ( 195 Pt, 13 C) coupling satellites.

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