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Phosphorus‐31 and platinum‐195 NMR studies of carboxylato‐bridged dinuclear platinum(II) complexes
Author(s) -
Kannan S.,
Jain V. K.
Publication year - 1990
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.1260281202
Subject(s) - chemistry , platinum , nuclear magnetic resonance spectroscopy , stereochemistry , medicinal chemistry , proton nmr , phosphorus , organic chemistry , catalysis
Carboxylato‐bridged dinuclear platinum(II) complexes of the type [Pt 2 X 2 (μ‐OOCR′) 2 (PR 3 ) 2 ] [X = Cl, I; R′ = CH 3 , CF 3 ; PR 3 = PEt 3 n , PPr 3 n , PBu 3 n , PMe 2 Ph, PMePh 2 , PPh 3 , P( p ‐Tol) 3 ] were prepared and investigated by 31 P and 195 Pt NMR spectroscopy. The NMR data indicate that there is considerable platinum‐platinum interaction in these complexes.