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An investigation of the keto‐enol tautomerism in 2‐acetyl‐1‐tetralone by 2D NMR spectroscopy
Author(s) -
Agrawal Pawan K.,
Thakur Raghunath S.,
Frahm August W.,
Schneider M.
Publication year - 1990
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.1260281105
Subject(s) - chemistry , tetralone , tautomer , keto–enol tautomerism , proton nmr , nuclear magnetic resonance spectroscopy , two dimensional nuclear magnetic resonance spectroscopy , carbon 13 nmr satellite , spectroscopy , dept , enol , stereochemistry , fluorine 19 nmr , organic chemistry , physics , quantum mechanics , catalysis
Long‐range CH correlation and long‐range selective proton decoupling (LRSPD), together with other standard NMR techniques, led to the complete 13 C and 1 H NMR spectral assignments of 2‐acetyl‐1‐tetralone and demonstrated its existence in the endo ‐enolic form.