Carbon‐13 and proton spectra of tetracyclododecanes: Long‐range steric effects | Zendy

Seidl P. R. | Zendy; Leal K. Z. | Zendy; Costa V. E. U. | Zendy; Poli N. D. | Zendy

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Carbon‐13 and proton spectra of tetracyclododecanes: Long‐range steric effects

Author(s) -

Seidl P. R.,

Leal K. Z.,

Costa V. E. U.,

Poli N. D.

Publication year - 1990

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.1260281007

Subject(s) - chemistry , steric effects , bicyclic molecule , spectral line , proton , reagent , carbon fibers , chemical shift , stereochemistry , range (aeronautics) , carbon 13 nmr , nmr spectra database , medicinal chemistry , organic chemistry , nuclear physics , physics , materials science , astronomy , composite number , composite material

The 1 H and 13 C spectra of endo‐endo ‐tetracyclo[6.1.1 3,6 .0 2,7 ]dodec‐4‐en‐10‐ol have been interpreted using shift reagents and HETCOR experiments. Carbon chemical shifts are compared with tetracyclic analogs and bicyclic model compounds. Evidence for upfield δ and ε effects of 3–5 ppm is presented.

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