Premium
Comparison of one‐ and two‐dimensional techniques in the unambiguous 13 C NMR spectral assignment of ellipticine and related indole derivatives
Author(s) -
Gogoll Adolf,
Plobeck Niklas A.
Publication year - 1990
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.1260280714
Subject(s) - chemistry , indole test , spectral line , nmr spectra database , stereochemistry , carbon 13 nmr , two dimensional nuclear magnetic resonance spectroscopy , nuclear magnetic resonance spectroscopy , computational chemistry , physics , astronomy
The 13 C NMR spectra of several indole derivatives have been completely assigned by reverse detected one‐bond and long‐range CH correlation spectra (HMQC) and by selective INEPT experiments. The resolution and sensitivity of the two techniques are discussed. As a result, the literature assignments for the previously known compounds have been revised.