1 H and  13 C NMR determination of the relative stereochemistry of the diastereomers resulting from the reaction of sily enol ethers with the 1‐ethoxy‐1‐propargylium dicobalt hexacarbonyl cation | Zendy

Montaña Pedrero Angel M. | Zendy; Nicholas Kenneth M. | Zendy

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1 H and 13 C NMR determination of the relative stereochemistry of the diastereomers resulting from the reaction of sily enol ethers with the 1‐ethoxy‐1‐propargylium dicobalt hexacarbonyl cation

Author(s) -

Montaña Pedrero Angel M.,

Nicholas Kenneth M.

Publication year - 1990

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.1260280604

Subject(s) - chemistry , diastereomer , alkoxy group , enol , stereochemistry , two dimensional nuclear magnetic resonance spectroscopy , enol ether , carbon 13 nmr , proton nmr , organic chemistry , catalysis , alkyl

The application of 1 H and 13 C NMR correlations and phase‐sensitive NOESY in the stereochemical assignment of four diastereoisomers of hexacarbonyl{μ‐η 4 ‐[2,4‐dimethyl‐2‐(1‐ethoxy‐2‐propyn‐1‐yl)‐8‐oxabicyclo [3.2.1] octan‐3‐one]}dicobalt‐(CoCo) is reported.

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