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Probing the mechanism of ligand exchange by two‐dimensional NMR spectroscopy
Author(s) -
HampdenSmith Mark J.,
Ruegger Heinz
Publication year - 1989
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.1260271202
Subject(s) - chemistry , nuclear magnetic resonance spectroscopy , phosphine , ligand (biochemistry) , spectroscopy , computational chemistry , nuclear magnetic resonance crystallography , fluorine 19 nmr , mechanism (biology) , platinum , stereochemistry , organic chemistry , catalysis , biochemistry , physics , receptor , philosophy , epistemology , quantum mechanics
The application of two‐dimensional chemical exchange NMR spectroscopy to the elucidation of ligand‐exchange mechanisms in inorganic complexes is addressed. Specific examples involving inter‐ and intra‐molecular phosphine exchange in platinum and mercury complexes are given, and the generality of the technique is discussed.