NMR spectra and stereochemistry of 1,5‐ and 1,6‐disubstituted perhydrooxazolo[3,4‐a] pyridines | Zendy

Crabb Trevor A. | Zendy; Trethewey Andrew N. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

NMR spectra and stereochemistry of 1,5‐ and 1,6‐disubstituted perhydrooxazolo[3,4‐a] pyridines

Author(s) -

Crabb Trevor A.,

Trethewey Andrew N.

Publication year - 1989

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.1260270320

Subject(s) - chemistry , alkyl , isopropyl , nuclear magnetic resonance spectroscopy , nmr spectra database , stereochemistry , two dimensional nuclear magnetic resonance spectroscopy , proton nmr , medicinal chemistry , spectral line , organic chemistry , physics , astronomy

13 C and 1 H NMR spectroscopy showed that with the exception of r‐1,t‐6,t‐8a‐1‐alkyl‐6‐ethylperhydrooxazolo[3,4‐a] pyridines (alkyl = ethyl, isopropyl) which adopt the O ‐inside cis‐fused conformation, all the other 1 ‐alkyl‐6‐ethyl‐ and 1‐alkyl‐ cis (H‐5, H ‐ 8a) ‐5‐ methyl ‐ perhydrooxazolo [3,4‐a] pyridines adopt trans‐fused conformations (CDCI 3 , 298 K).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research