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DEPT‐related sequences for selective long‐range heteronuclear chemical shift correlation spectroscopy
Author(s) -
Kövér Katalin E.,
Batta Gy.
Publication year - 1989
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.1260270112
Subject(s) - heteronuclear molecule , dept , chemistry , heteronuclear single quantum coherence spectroscopy , pulse sequence , two dimensional nuclear magnetic resonance spectroscopy , range (aeronautics) , protonation , spectroscopy , nuclear magnetic resonance spectroscopy , nuclear magnetic resonance , spectral line , analytical chemistry (journal) , stereochemistry , physics , organic chemistry , materials science , ion , quantum mechanics , astronomy , composite material
DEPT‐related sequences are proposed which suppress the generally unnecessary direct proton‐carbon correlations from the long‐range optimized heteronuclear chemical shift correlation spectra. One‐bond modulation of long‐range response intensities is removed through the use of a BIRD pulse train. It is demonstrated that these modified sequences are superior to the original 2D DEPT experiment for the detection of long‐range connectivities of protonated carbons.
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