Determination of the stereochemistry of isoxazolidinium salts by nuclear Overhauser effect difference spectroscopy | Zendy

Liguori A. | Zendy; Ottanà R. | Zendy; Romeo G. | Zendy; Rotondo E. | Zendy; Sindona G. | Zendy; Uccella N. | Zendy

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Determination of the stereochemistry of isoxazolidinium salts by nuclear Overhauser effect difference spectroscopy

Author(s) -

Liguori A.,

Ottanà R.,

Romeo G.,

Rotondo E.,

Sindona G.,

Uccella N.

Publication year - 1988

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.1260261108

Subject(s) - chemistry , nuclear overhauser effect , steric effects , nuclear magnetic resonance spectroscopy , spectroscopy , ring (chemistry) , two dimensional nuclear magnetic resonance spectroscopy , stereochemistry , nuclear magnetic resonance , organic chemistry , physics , quantum mechanics

The configurations of some isoxazolidinium salts have been determined by nuclear Overhauser effect difference spectroscopy (NOEDS). The stereochemical findings give a good explanation of the different reactivities experienced in the five‐membered ring‐opening process as a function of the steric requirement of the system.

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