Structure elucidation of a hexahydrocannabinol derivative via  13 C 13 C homonuclear correlation and  1 H 13 C heteronuclear correlation with proton detection | Zendy

Zetta Lucia | Zendy; De Marco Antonio | Zendy; Anklin Clemens | Zendy; Cornia Mara | Zendy; Casiraghi Giovanni | Zendy

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Structure elucidation of a hexahydrocannabinol derivative via 13 C 13 C homonuclear correlation and 1 H 13 C heteronuclear correlation with proton detection

Author(s) -

Zetta Lucia,

De Marco Antonio,

Anklin Clemens,

Cornia Mara,

Casiraghi Giovanni

Publication year - 1987

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.1260251213

Subject(s) - homonuclear molecule , heteronuclear molecule , chemistry , proton , carbon 13 , coupling constant , spectral line , derivative (finance) , stereochemistry , analytical chemistry (journal) , nuclear magnetic resonance spectroscopy , molecule , physics , nuclear physics , organic chemistry , particle physics , astronomy , financial economics , economics

Two‐dimensional carbon‐carbon correlated spectra (2D‐INADEQUATE) and proton‐carbon correlated spectra obtained with proton detection have been used to determine the absolute configuration and conformation of a hexahydrocannabinol derivative obtained with highly stereocontrolled synthesis. From the proton‐proton coupling constants the junction between rings B and C was found to be trans and the relative stereodisposition of C‐10a, C‐9 and C‐6a was deduced to be R .

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