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2D NMR studies of the phenyldichloroarsine—british anti—lewisite adduct
Author(s) -
Dill Kilian,
Adams Earle R.,
O'Connor Richard J.,
McGown Evelyn L.
Publication year - 1987
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.1260251211
Subject(s) - chemistry , homonuclear molecule , adduct , nuclear magnetic resonance spectroscopy , ring (chemistry) , hydroxymethyl , chemical shift , stereochemistry , carbon 13 nmr satellite , crystallography , fluorine 19 nmr , molecule , organic chemistry
One‐ and two‐dimensional NMR spectroscopy was used to determine the structure of the phenyldichloroarsine‐British anti‐lewisite adduct. The major component had the hydroxymethyl group in the anti orientation with respect to the phenyl ring on the arsenous atom. This structure was based on the chemical shifts of the 1 H and 13 C resonances and on the respective homonuclear coupling constants.