Assignment of carbonyl groups and sequence analysis in peptides by inverse correlation using long‐range couplings | Zendy

Bermel Wolfgang | Zendy; Griesinger Christian | Zendy; Kessler Horst | Zendy; Wagner Klaus | Zendy

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Assignment of carbonyl groups and sequence analysis in peptides by inverse correlation using long‐range couplings

Author(s) -

Bermel Wolfgang,

Griesinger Christian,

Kessler Horst,

Wagner Klaus

Publication year - 1987

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.1260250410

Subject(s) - heteronuclear molecule , chemistry , inverse , sequence (biology) , range (aeronautics) , stereochemistry , pulse sequence , peptide , amino acid , computational chemistry , nuclear magnetic resonance spectroscopy , nuclear magnetic resonance , biochemistry , materials science , geometry , mathematics , physics , composite material

Inverse heteronuclear shift correlation via long‐range coupling to the carbonyl carbons of the cyclic hexapeptide cyclo(‐Phe 11 ‐Thr10‐Aia9‐Trp8‐Phe/‐D‐Pro6‐) allows the sequential assignment of the amino acids. This experiment has a higher sensitivity than the conventional COLOC sequence.

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