Solid‐state tin‐119 NMR spectroscopy: The first observations of (Tin‐119, tin‐117) coupling constants | Zendy

Harris Robin K. | Zendy; Mitchell Terence N. | Zendy; Nesbitt Geoffrey J. | Zendy

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Solid‐state tin‐119 NMR spectroscopy: The first observations of (Tin‐119, tin‐117) coupling constants

Author(s) -

Harris Robin K.,

Mitchell Terence N.,

Nesbitt Geoffrey J.

Publication year - 1985

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.1260231211

Subject(s) - tin , chemistry , spectral line , coupling constant , benzene , solid state , spectroscopy , nmr spectra database , nuclear magnetic resonance spectroscopy , coupling (piping) , analytical chemistry (journal) , stereochemistry , organic chemistry , metallurgy , physics , materials science , quantum mechanics , particle physics , astronomy

(Tin‐119, tin‐117) coupling satellites are visible in the CP/MAR spectra of tetrakis(trimethylstannyl)methane and of a series of tetrastannacyclohexanes, the values in the solid and solution states being equal within experimental error. The single signal from the former compound has a line width of only 28 H z . The broad lines (Δν 1/2 320 H z ) obtained for 1,4‐bis(trimethylstannyl)benzene precluded the observation of 5 J (SnSn).

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