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Conformational analysis of N ‐acylazabicyclooctanes
Author(s) -
Sohár P.,
Pelczer I.,
Váczi I.,
Tombor A.,
Matolcsy G.
Publication year - 1985
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.1260230705
Subject(s) - chemistry , conformational isomerism , substituent , amide , octane , nuclear magnetic resonance spectroscopy , dept , stereochemistry , solvent , computational chemistry , organic chemistry , molecule
Abstract N ‐Acyl derivatives of 1,3,3‐trimethyl‐6‐azabicyclo[3.2.1]octane were synthesized as compounds with potential pesticidal activity. The conformation of the starting compound and the substituent dependence of the amide rotamers of the acyl derivatives were studied by 1 and 13 C NMR spectroscopy, making use of solvent effects (ASIS) and DR, DNOE and DEPT measurements.