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17 O NMR spectra of tertiary alcohols, ethers, sulfoxides and sulfones in the cyclohexyl and 5‐substituted 1,3‐dioxanyl series and related compounds
Author(s) -
Manoharan Muthiah,
Eliel Ernest L.
Publication year - 1985
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.1260230403
Subject(s) - chemistry , cyclohexane , norbornane , nmr spectra database , organic chemistry , tertiary alcohols , medicinal chemistry , tetrahydropyran , nuclear magnetic resonance spectroscopy , carbon 13 nmr , stereochemistry , spectral line , alcohol , ring (chemistry) , physics , astronomy
Abstract 17 O NMR spectra of fifteen cyclohexane‐derived tertiary alcohols and related ethers and acetals, six 1,3‐dioxane‐derived orthoesters, four cyclohexane‐ and 1,3‐dioxane‐derived sulfones and the four corresponding sulfoxides, three acyclic sulfones, six alcohols derived from norbornane and 1,3‐dithiane and two esters have been recorded. Attention is drawn to δ‐compression effects and saturation effects in several of these compounds.