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119 Sn and 1 H NMR of the novel complexes [IrH(SnCl 3 ) 5 ] 3‐ and [RhH(SnCl 3 ) 5 ] 3‐
Author(s) -
Yamakawa Tetsu,
Shinoda Sumio,
Saito Yasukazu,
Moriyama Hiroshi,
Pregosin Paul S.
Publication year - 1985
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.1260230315
Subject(s) - chemistry , dehydrogenation , hydride , nuclear magnetic resonance spectroscopy , acetone , catalysis , medicinal chemistry , crystallography , hydrogen , stereochemistry , organic chemistry
New anionic complexes, [IrH(SnCl 3 ) 5 ] 3‐ and [RhH(SnCl 3 ) 5 ] 3‐ , in which the hydride ligands are stabilized only by SnCl 3 − ligands, have been characterized by 119 Sn and 1 H NMR spectroscopy. These pentakis SnCl 3 − complexes are contained in catalyst solutions for the liquid‐phase dehydrogenation of propan‐2‐ol yielding acetone and dihydrogen.