119 Sn and  1 H NMR of the novel complexes [IrH(SnCl 3 ) 5 ] 3‐  and [RhH(SnCl 3 ) 5 ] 3‐ | Zendy

Yamakawa Tetsu | Zendy; Shinoda Sumio | Zendy; Saito Yasukazu | Zendy; Moriyama Hiroshi | Zendy; Pregosin Paul S. | Zendy

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119 Sn and 1 H NMR of the novel complexes [IrH(SnCl 3 ) 5 ] 3‐ and [RhH(SnCl 3 ) 5 ] 3‐

Author(s) -

Yamakawa Tetsu,

Shinoda Sumio,

Saito Yasukazu,

Moriyama Hiroshi,

Pregosin Paul S.

Publication year - 1985

Publication title -

magnetic resonance in chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.483

H-Index - 72

eISSN - 1097-458X

pISSN - 0749-1581

DOI - 10.1002/mrc.1260230315

Subject(s) - chemistry , dehydrogenation , hydride , nuclear magnetic resonance spectroscopy , acetone , catalysis , medicinal chemistry , crystallography , hydrogen , stereochemistry , organic chemistry

New anionic complexes, [IrH(SnCl 3 ) 5 ] 3‐ and [RhH(SnCl 3 ) 5 ] 3‐ , in which the hydride ligands are stabilized only by SnCl 3 − ligands, have been characterized by 119 Sn and 1 H NMR spectroscopy. These pentakis SnCl 3 − complexes are contained in catalyst solutions for the liquid‐phase dehydrogenation of propan‐2‐ol yielding acetone and dihydrogen.

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