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Assessing the potential of fast amplitude modulation pulses for improving triple‐quantum magic angle spinning NMR spectra of half‐integer quadrupolar nuclei
Author(s) -
Morais C. M.,
Lopes M.,
Fernandez C.,
Rocha J.
Publication year - 2003
Publication title -
magnetic resonance in chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.483
H-Index - 72
eISSN - 1097-458X
pISSN - 0749-1581
DOI - 10.1002/mrc.1238
Subject(s) - chemistry , spectral line , magic angle spinning , amplitude , quadrupole , half integer , quantum , andalusite , sideband , coherence (philosophical gambling strategy) , analytical chemistry (journal) , molecular physics , atomic physics , nuclear magnetic resonance spectroscopy , condensed matter physics , optics , physics , stereochemistry , quantum mechanics , organic chemistry , petrology , metamorphism , geology , microwave
A comprehensive experimental and numerical study of the potential of fast amplitude (FAM) irradiation for improving the triple‐quantum (3Q) magic angle spinning (MAS) NMR spectra of half‐integer $I > {1 \over 2}$ nuclei ( 23 Na, 27 Al, 45 Sc, 93 Nb) was carried out. Materials of academic and industrial importance, such as infrared‐emitter Na 3 YSi 3 O 9 , microporous aluminophosphate VPI‐5, mineral andalusite, calcined kaolinite, Sc 2 O 3 and relaxor ferroelectric PMN, were investigated. It was found that FAM pulses are indeed of practical relevance and particularly useful for the observation of the NMR resonances given by nuclei in distorted local environments (large quadrupole coupling constants). In addition, a novel strategy for the optimization of the FAM‐II MQ MAS NMR experiment, which improves the multiple‐ to single‐quantum coherence transfer efficiency, is also reported. Copyright © 2003 John Wiley & Sons, Ltd.