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Microwave dielectric properties of pure and Zr 4+ doped lead calcium iron niobate substrates for microwave devices and antenna applications
Author(s) -
Puri Maalti,
Bahel Shalini,
Narang Sukhleen Bindra
Publication year - 2015
Publication title -
microwave and optical technology letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.304
H-Index - 76
eISSN - 1098-2760
pISSN - 0895-2477
DOI - 10.1002/mop.29278
Subject(s) - materials science , analytical chemistry (journal) , tetragonal crystal system , microwave , dielectric , relative permittivity , permittivity , dissipation factor , ion , dielectric loss , doping , crystal structure , crystallography , chemistry , optoelectronics , physics , organic chemistry , chromatography , quantum mechanics
ABSTRACT Two series of (Pb 1‐x Ca x )(Fe 0.5 Nb 0.5 )O 3 for x = 0.00, 0.20, 0.40, 0.45, 0.50, 0.55, 0.60, and (Pb 0.45 Ca 0.55 )(Fe 0.5 Nb 0.5 ) 1‐y Zr y O 3 for 0.00 ≤ y ≤ 0.15 in the steps of 0.03 have been synthesized using columbite precursor method. X‐ray diffraction patterns show that all the solid solutions have tetragonal symmetry. Microwave dielectric properties of synthesized solid solutions have been investigated in X‐band (8.2–12.4 GHz). The substitution of Zr 4+ ions at B‐site of (Pb 0.45 Ca 0.55 )(Fe 0.5 Nb 0.5 ) 1‐y Zr y O 3 decreased the loss tangent but did not remarkably affect the relative permittivity. The temperature coefficient of relative permittivity decreased with the substitution of Ca 2+ ion for Pb 2+ ions at A‐site in first series. The temperature coefficient of relative permittivity further decreased with the substitution of Zr 4+ ions at B‐site in second series. The reflection loss decreased but VSWR and bandwidth improved slightly with the substitution of Zr contents in second series. The present materials can be used as substrate for microwave devices and antennas applications. © 2015 Wiley Periodicals, Inc. Microwave Opt Technol Lett 57:2151–2155, 2015