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Nanostructured rhodium: electrochemical behaviour and electrodeposition from low‐temperature carbamide‐ and acetamide‐containing melts
Author(s) -
Kochetova S.,
Savchuk A.,
Malyshev V.,
GonEskar M.,
Solianyk L.
Publication year - 2015
Publication title -
materialwissenschaft und werkstofftechnik
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.285
H-Index - 38
eISSN - 1521-4052
pISSN - 0933-5137
DOI - 10.1002/mawe.201500400
Subject(s) - rhodium , acetamide , electrochemistry , dissolution , chemistry , nanoparticle , inorganic chemistry , chloride , nuclear chemistry , materials science , catalysis , organic chemistry , electrode , nanotechnology
It was ascertained that in carbamide‐ and acetamide‐chloride melts at anodic dissolution of rhodium some mixed complexes [Rh(NH 3 ) 4 Cl 2 ] + form which are of quasi‐octahedral structure and D4h symmetry. During cathodic reduction of the obtained complexes Rh(III) in the investigated melts the synthesis of nanoparticles Rh was carried out as well as nanocoating of Fe, Cu and Mo by them.