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Constitution, microstructure, mechanical properties, and performance of magnetron‐sputtered carbon films with additions of silicon
Author(s) -
Bauer C.,
Leiste H.,
Stüber M.,
Ulrich S.,
Holleck H.
Publication year - 2003
Publication title -
materialwissenschaft und werkstofftechnik
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.285
H-Index - 38
eISSN - 1521-4052
pISSN - 0933-5137
DOI - 10.1002/mawe.200300677
Subject(s) - materials science , silicon , microstructure , graphite , substrate (aquarium) , sputter deposition , carbon fibers , metallurgy , composite material , residual stress , silicon carbide , amorphous solid , vickers hardness test , amorphous carbon , carbide , sputtering , thin film , nanotechnology , crystallography , chemistry , composite number , oceanography , geology
Amorphous carbon films with additions of silicon were deposited by non‐reactive magnetron sputtering on WC‐Co hard metal and on silicon substrates. The targets were hot‐pressed, homogenous mixtures of graphite and silicon carbide powder. Additional argon ion bombardment of the growing film was applied by a substrate bias varied between 0V and ‐800 V. The deposited amorphous carbon films with two different silicon contents (5 at.% and 23 at.% respectively) were characterised with respect to their microstructure, density, thickness, residual stress, Vickers hardness, Young's modulus, critical load of failure, friction coefficient, and wear behaviour. The residual stress of the carbon films could be remarkably lowered by silicon additions (23 at.%). The hardness reached high values (2200 HV0.05) and the friction coefficient for unlubricated sliding friction against a steel (1.3505) counterpart was as low as 0.06.